Assembly of a Flexible 2,2′-Oxydibenzoate and Silver(I) Ions to a Novel 3D Supramolecular Framework: Syntheses, Structure and Properties
نویسندگان
چکیده
Self-assembly of silver(I) cations, flexible 2,2′-oxydibenzoate anions (L2−), and 1,2-bis(4pyridyl)ethane (bpa) ligands affords a new three-dimensional supramolecular architecture, {[Ag2(L)(bpa)2]·(H2O)4}n (1), which has been characterized by elemental analysis, IR, TGA, PXRD, and single-crystal X-ray diffraction. Complex 1 exhibits layers further connected through hydrogen bonding and π · · ·π stacking interactions. Its photoluminescence was also investigated.
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